Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义     

黄式庭  于晓飞  吕志成  刘家军  李永胜  杜泽忠  吕鑫  孙海瑞  杜轶伦 《吉林大学学报(地球科学版)》2020,50(5):1387-1403

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一，其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征，将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主，粒度为0.50~1.50 mm，贫As、Au；毒砂含量极少，呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出，含砷黄铁矿多为立方体、五角十二面体，粒度为0.30~1.00 mm，富As、Au；该阶段矿化最为强烈，毒砂主要形成于此时期，多呈棱柱状、柱状、放射状集合体，显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出，黄铁矿多呈长条状，以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱，毒砂、黄铁矿含量极少，为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰，均值为-3.3‰；Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰，均值为-3.3‰；Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间，均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆，混入了部分地层硫。综合前人研究成果，认为成矿早期至晚期，成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境，硫源充足；Ⅱ阶段为贫S富As的高氧逸度环境，由于大气降水对地层的淋滤渗透，混入富As流体，Au可能与As结合形成Au-As络合物，在成矿有利部位富集沉淀；Ⅲ阶段成矿元素种类丰富，体系为富S贫As的弱还原环境，Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。  相似文献   

天然裂缝影响下的花岗岩水力裂缝扩展数值模拟     

王璜  王贵玲  岳高凡  甘浩男 《地质学报》2020,94(7):2124-2130

水力压裂技术是成功实现干热岩资源开发利用的重要手段之一，数值模拟技术能够精准预测水力裂缝扩展。针对典型花岗岩，借助黏性单元法，分别模拟了致密花岗岩和天然裂缝存在情况下的水力裂缝扩展特征，得出以下结论：致密花岗岩的水力裂缝形态单一，天然裂缝的存在增加了压裂后裂缝的复杂性；致密花岗岩水力裂缝拓展主要分为憋压和拓展两个交替往复的阶段，当存在天然裂隙时，水力压裂过程会变得复杂；天然裂缝存在时，水力裂缝的缝长和缝宽分别为致密花岗岩的5. 7倍和1. 7倍；缝网的形成需要借助复杂的压裂工艺实现。研究结果可以为增强型地热系统(EGS)储层水力刺激工作提供理论支持。  相似文献   

基于波形特征的露天钼矿微震事件的识别分析——以卓资山钼矿为例     

赵艳红  包金哲  王树波  翟浩  魏建民  杨智升  张晖  赵铁锁  苏日亚  王磊  王鑫  贾昕晔  刘芳 《震灾防御技术》2019,14(3):662-676

基于前人研究成果以及现场的实测结果，采用卓资山露天钼矿微震监测项目产出资料，提取了5类微震事件的波形特征和时频特征。波形特征显示:微地震的振幅、辐射均匀性和频率变化特征表明微地震是由于岩层受到单力偶和剪切力作用破裂而产生；爆破具有P波初动方向向上、S波不易识别的特点，包含“初震段、主震段、尾波段”三段变化形态；小型边坡滑坡波事件属楔体滑坡，是由多个“加速—缓冲—终止”构成，波形是由包络线呈“V”字形的多组脉冲波列组成；机械开采震动事件具有自振能量不变、脉冲幅度相差很大、持续时间间隔不确定的特点；运输车辆波形振幅具有形态“弱—强—弱”、等频率、包络线呈多段纺锤形的特征。时频空间分布可以分为相对独立、界限分明的两类:一类包含微地震、爆破、机械开采、小型边坡滑坡事件，另一类只包含车辆运输事件。  相似文献   

Temporal and Spatial Dynamics Analysis of Grassland Ecosystem Pressure in Kazakhstan     

WEN Xin  YAN Huimin  XIE Xiaoping  DU Wengpeng  LAI Chenxi  ZHEN Lin 《资源与生态学报(英文版)》2019,10(6):667-675

Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.  相似文献   

汶川MS8.0大震前后鲜水河断裂带滑动及其西部地壳形变的动态变化     

陈欣  杨国华 《华北地震科学》2020,38(3):27-31,37

基于鲜水河断裂带及邻近区域GPS资料,以发生汶川MS8.0大震的2008年为时间节点,利用视错动变形系统分析模型研究了鲜水河断裂带及邻区不同时段的滑动与区域形变活动特征,结果表明:汶川大震前后鲜水河断裂带构造活动的动态变化是显著的,其西部地区地壳形变的动态变化也较清晰,这些不仅说明了汶川大震的孕育在较大的空间范围存在不同特征的形变与构造活动,同时其西部地区也存在着疑似断裂带形变中心的地壳动态变化,这可能与特定的构造和动力环境密切相关,为我们识别大震前兆提供了更多的可能。  相似文献   

基于噪声谱比法的内蒙古西部地区台站场地响应研究     

张珂  王鑫  王树波  张红才  宋晓燕 《大地测量与地球动力学》2020,40(6):646-651

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。  相似文献   

Comparisons of Salinity Adaptation in Terms of Growth,Body Composition,and Energy Budget in Juveniles of Rainbow and Steelhead Trouts (Oncorhynchus mykiss)     

XIONG Yinghuai  WANG Xin  DONG Shuanglin  WANG Fang  YANG Jingwen  ZHOU Yangen 《中国海洋大学学报(英文版)》2019,(2)

This study examined the effect of different salinities(0, 5, 10, 15, 20, 25 and 30) on the growth performance and energy budget of juveniles of two different ecotypes of Oncorhynchus mykiss, landlocked rainbow trout and anadromous steelhead trout. In the 42 d experiment, fish were cultured in three replicate tanks per salinity treatment(eight fish per tank). At the end of the experiment, the growth of rainbow and steelhead trouts was significantly higher at salinities of 5 and 10, respectively, than at all other salinities. The protein, lipid and energy content of both ecotypes declined with the increase of salinity. Based on their energy budgets, the percentage of energy consumed for growth by rainbow and steelhead trouts were significantly higher at salinities of 5(34.00% ±1.69%) and 10(43.76% ± 1.29%), respectively, than at all other salinities. The percentage of energy consumed for respiration by rainbow and steelhead trouts was lower at salinities of 5(54.90% ± 1.77%) and 10(46.73% ± 0.62%), respectively, than at all other salinities. Our results indicated that the salinity adaptation ability of juvenile steelhead trout was slightly better than that of juvenile rainbow trout, and salinities of 10 and 5, respectively, were most suitable for growth of these two fishes.  相似文献   

湍流度随高度的变化及其对城市宏观地形的依赖     

李大全  孙武  欧阳睿康  黄盛  高梦媛  李庆祥  黄启明 《热带地理》2019,39(3):365-376

分别构建广州主建成区垂直比例尺为1﹕2 000、1﹕1 000和1﹕500的3个建筑物模型，利用大型边界层风洞，在西北和东南两风向下，基于中性流模拟分析了复杂城市地形下湍流度随高度的变化及其对宏观地形的依赖。结果表明：风廓线指数α与不同高度的湍流度之间的关系密切，利用现有模型，根据4类粗糙度边界层和不同垂直比例尺，可确定相应的湍流度随高度变化模型的主要系数，预测精度高。城市地形下最大湍流度面发育在0~0.2 h之间狭窄的范围内。用湍流度形态指数β来表征湍流度随高度的变化，无论城市屋脊还是平坦地形，随着风程区的延伸，廓线的指数α升高，湍流度形态指数β降低。表明同一高度湍流度值具有由迎风区、丘顶区向背风区增高，沿风程逐渐增大的规律，对地形部位和风程的依赖性强，与来流翻越简单地形时的特征一致。  相似文献   

三峡水库和长江中下游通江湖泊(洞庭湖和鄱阳湖)草鱼、鲢的孵化日期及早期生长特征     

张文武  马琴  黎明政  张晨  高欣 《湖泊科学》2020,32(3):804-812

三峡水库以及上游江段形成的河—库生态系统与长江中下游洞庭湖和鄱阳湖的江湖生态系统都是四大家鱼的重要栖息地,有相似性也有差异.2017年7—8月在三峡水库、洞庭湖和鄱阳湖利用地笼、虾笼、高网和迷魂阵采集草鱼和鲢幼鱼样本,观测耳石日轮,分析三峡水库和通江湖泊草鱼和鲢幼鱼的繁殖时间和早期生长特征及差异,探讨相应的保护措施.结果显示,三峡水库、洞庭湖和鄱阳湖采集草鱼幼鱼的孵化日期分别为4月24日—5月25日、5月21日—6月26日和5月4日—5月28日;鲢幼鱼的孵化日期分别为4月10日—6月12日、5月25日—6月19日和5月9日—6月12日.三峡水库、洞庭湖和鄱阳湖草鱼样本的体长增长率分别为1.04、1.84和1.64 mm/d,微耳石的沉积率分别为3.41、5.41和4.77μm/d;鲢幼鱼的体长增长率分别为1.10、2.87和1.96 mm/d,微耳石沉积率分别为2.96、7.17和4.57μm/d.洞庭湖草鱼和鲢的体长增长率和耳石沉积率均显著大于三峡水库;鄱阳湖鲢的体长增长率和耳石沉积率均显著大于三峡水库,而草鱼的体长增长率和耳石沉积率则与三峡水库没有显著差异.结果表明,三峡水库蓄水后长江中游干流草鱼和鲢的繁殖时间明显滞后;洞庭湖和鄱阳湖的草鱼和鲢幼鱼生长更快.目前,长江全面禁渔正在逐步实施,预期将对恢复鱼类资源起到重要的作用.除了全面禁渔之外,还建议保护和修复鱼类栖息地;减少江湖阻隔,灌江纳苗;增殖放流亲鱼;开展生态调度,促进鱼类繁殖.  相似文献